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Solid-Liquid Phase Equilibria in the Aqueous System Containing Potassium, Magnesium, and Borate at 308.15 K

摘要:Experimental studies on the solubility, density, refractive index, and pH value in the aqueous system containing potassium, magnesium, and borate at 308.15 K were determined with the method of isothermal dissolution equilibrium. Based on the experimental results, the diagrams of solubility, density, refractive index, and pH value in this system were plotted. We found that there were one eutectic point and two crystallization regions corresponding to the large area of inderite (L + Mg2B6O11·15H2O) and the relatively small area of potassium borate tetrahydrate (L + K2B4O7 ·4H2O), respectively. Neither double salt nor solid solution was found in this system. The physicochemical properties (density, refractive index, and pH value) in solution at 308.15 K changed regularly with increasing potassium borate concentration. The calculated values of density and refractive index using empirical equations of the aqueous system were in good agreement with the experimental values.

关键词:
  • stable  
  • phase  
  • equilibrium  
  • diagram  
  • solubility  
  • physicochemical  
  • property  
作者:
SHI; Chun-cheng; YANG; Juan; WANG; Shi-qiang; ZHAO; Dong; GUO; Ya-fei; DENG; Tian-long
单位:
College; of; Marine; and; Environmental; Sciences; Tianjin; University; of; Science; and; Technology; Tianjin; 300457; China; Tianjin; Key; Laboratory; of; Marine; Resources; and; Chemistry; Tianjin; 300457; China
刊名:
盐湖研究

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期刊名称:盐湖研究

盐湖研究杂志紧跟学术前沿,紧贴读者,国内刊号为:63-1026/P。坚持指导性与实用性相结合的原则,创办于1992年,杂志在全国同类期刊中发行数量名列前茅。