摘要:基于HFR和LS-dependent(LS-D)的HFR自洽场方法,详细研究了Rn等电子系列离子的5f电子径向波函数的性态,分析了Rn等电子系列离子5f电子径向波函数的塌缩规律,并在此基础上进一步讨论了Rn等电子系列离子的nf(n≥6)波函数和5d10→5d9nf1P(6≤n≤10)跃迁振子强度的变化规律.结果表明,5f波函数的蹋缩与谱相有强烈的依赖关系;5f波函数的部分塌缩引起Ra2+离子5d10→5d9nf1P(6≤n≤10)跃迁振子强度的突增;5f波函数完全塌缩后,跃迁振子强度主要集中在5d10→5f1P能级.
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